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Configurational Stability of 1,1′-Bi-2-naphthol in Superacid System HSO3F-SbF5-SO2ClF.
- Source :
-
Russian Journal of Organic Chemistry . May2018, Vol. 54 Issue 5, p792-794. 3p. - Publication Year :
- 2018
-
Abstract
- Although 1,1′-bi-2-naphthol (BINOL) is known to racemize in aqueous mineral acids and much more readily in superacids, it retains its initial configuration in one of the strongest superacid system, HSO3F-SbF5-SO2ClF due to protective C8,C8′-diprotonation. [ABSTRACT FROM AUTHOR]
- Subjects :
- *BINAPHTHOL
*SUPERACIDS
*ENANTIOMERS
*CHEMICAL bonds
*CHEMICAL structure
Subjects
Details
- Language :
- English
- ISSN :
- 10704280
- Volume :
- 54
- Issue :
- 5
- Database :
- Academic Search Index
- Journal :
- Russian Journal of Organic Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 130552267
- Full Text :
- https://doi.org/10.1134/S1070428018050214