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Catalytic behavior of magnetic Ni-Zn alloy.
- Source :
-
Research on Chemical Intermediates . Jul2018, Vol. 44 Issue 7, p4149-4161. 13p. 1 Black and White Photograph, 3 Charts, 9 Graphs. - Publication Year :
- 2018
-
Abstract
- Ni-Zn alloy with various compositions of zinc was synthesised using a sodium borohydride-assisted chemical reduction method. The as-synthesised Ni-Zn alloy samples were annealed at 673 K for 2 h in nitrogen atmosphere. The atomic absorption spectroscopy measurement reveals the zinc-rich composition in all alloy samples. Field emission scanning electron microscopy shows that the surface morphology of Ni-Zn alloys has a flake-like nature. The X-ray diffraction pattern of as-synthesised samples shows the presence of nickel hydroxide while the annealed samples show formation of Ni2Zn11 phase. The phase transition temperature of as-synthesised Ni-Zn alloy was observed using differential scanning calorimetry and crystallization temperature changes with zinc composition was also examined. The room temperature magnetic behaviour of both as-synthesised and annealed samples was studied using vibrating sample magnetometer. This shows that as-synthesised samples have a weak ferromagnetic nature and annealed samples have a soft ferromagnetic nature. The decreasing magnetization value and Curie temperature with zinc composition was observed. The catalytic activity of Ni-Zn alloy was studied for the reduction of 4-nitrophenol. The rate constant value changes with zinc composition in the alloy. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 09226168
- Volume :
- 44
- Issue :
- 7
- Database :
- Academic Search Index
- Journal :
- Research on Chemical Intermediates
- Publication Type :
- Academic Journal
- Accession number :
- 130147768
- Full Text :
- https://doi.org/10.1007/s11164-018-3360-x