Back to Search
Start Over
Linker-Directed Assembly of Twisted ortho-Phenylene-Based Macrocycles.
- Source :
-
Organic Letters . 6/1/2018, Vol. 20 Issue 11, p3327-3331. 5p. - Publication Year :
- 2018
-
Abstract
- o-Phenylene tetramers have been coassembled with linkers into macrocycles through imine condensation. Variation of linker connectivity and length allows both [1 + 1] and [2 + 2] macrocycles to be obtained, complementing (previously reported) [3 + 3] macrocycles. For the [1 + 1] macrocycles, linker length has a clear effect on o-phenylene geometry and macrocycle stability. For the [2 + 2] macrocycles, both homo- and heterochiral configurations are observed, suggesting limited communication of helix handedness in these systems. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 15237060
- Volume :
- 20
- Issue :
- 11
- Database :
- Academic Search Index
- Journal :
- Organic Letters
- Publication Type :
- Academic Journal
- Accession number :
- 130010678
- Full Text :
- https://doi.org/10.1021/acs.orglett.8b01237