Back to Search
Start Over
Flexible poly(ethylene carbonate)/garnet composite solid electrolyte reinforced by poly(vinylidene fluoride-hexafluoropropylene) for lithium metal batteries.
- Source :
-
Journal of Power Sources . Jul2018, Vol. 392, p232-238. 7p. - Publication Year :
- 2018
-
Abstract
- Solid-state electrolytes with high ionic conductivities, great flexibility, and easy processability are needed for high-performance solid-state rechargeable lithium batteries. In this work, we synthesize nanosized cubic Li 6.25 Al 0.25 La 3 Zr 2 O 12 (LLZO) by solution combustion method and develop a flexible garnet-based composite solid electrolyte composed of LLZO, poly(ethylene carbonate) (PEC), poly(vinylidene fluoride-hexafluoropropylene) (P(VdF-HFP) and lithium bis(fluorosulfonyl)imide (LiFSI)). In the flexible composite solid electrolytes, LLZO nanoparticles, as ceramic matrix, have a positive effect on ionic conductivities and lithium ion transference number ( t Li+ ). PEC, as a fast ion-conducting polymer, possesses high t Li+ inherently. P(VdF-HFP), as a binder, can strengthen mechanical properties. Consequently, the as-prepared composite solid electrolyte demonstrates high t Li+ (0.82) and superb thermal stability (remaining LLZO matrix after burning). All-solid-state LiFePO 4 |Li cells assembled with the flexible composite solid electrolyte deliver a high initial discharge specific capacity of 121.4 mAh g −1 and good cycling stability at 55 °C. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 03787753
- Volume :
- 392
- Database :
- Academic Search Index
- Journal :
- Journal of Power Sources
- Publication Type :
- Academic Journal
- Accession number :
- 129869882
- Full Text :
- https://doi.org/10.1016/j.jpowsour.2018.05.006