Back to Search
Start Over
Bio‐inspired Domino oxa‐Michael/Diels–Alder/oxa‐Michael Dimerization of para‐Quinols.
- Source :
-
Angewandte Chemie International Edition . 5/22/2018, Vol. 57 Issue 21, p6198-6202. 5p. - Publication Year :
- 2018
-
Abstract
- Abstract: A bio‐inspired, pyrrolidine‐mediated, dimerization of para‐quinols has been developed. It represents one of the most complex, yet general, dimerization reactions ever disclosed, selectively forming four new bonds, four new rings, and eight new contiguous stereogenic centres. The para‐quinol starting materials are easily handled, bench‐stable compounds, accessed in just one step from aromatic feedstocks. The reaction can be scaled up to give grams of polycyclic material, primed for further elaboration. [ABSTRACT FROM AUTHOR]
- Subjects :
- *DIMERIZATION
*HYDROQUINONE
*DIELS-Alder reaction
*POLYCYCLIC compounds
*PYRROLIDINE
Subjects
Details
- Language :
- English
- ISSN :
- 14337851
- Volume :
- 57
- Issue :
- 21
- Database :
- Academic Search Index
- Journal :
- Angewandte Chemie International Edition
- Publication Type :
- Academic Journal
- Accession number :
- 129739381
- Full Text :
- https://doi.org/10.1002/anie.201802125