Roles of Fe[sbnd]Ni nanoparticles and SrLaFeO4 substrate in the performance and reliability of a composite anode prepared through in-situ exsolution for intermediate temperature solid oxide fuel cells (I).

A composite anode composing of in-situ exsolved Fe Ni alloy (FNA) nanoparticles and Ruddlesden-Popper perovskite SrLaFeO 4 (SLF) substrate has been prepared by reducing La 0.5 Sr 0.5 Fe 0.8 Ni 0.20 O 3-δ (LSFN) perovskite precursor in humidified H 2 (3% H 2 O) at 800 °C. Roles of FNA and SLF, respectively, in performance and stability of the anode are systematically studied. The electric conductivity of the reduced LSFN and single cell performance of the composite (SLF-FNA) are examined in comparison with those of the SrLaFeO 4-δ (SLFO 4 ) anode alone. The significantly improved performance of the composite anode cell at lower temperatures (<700 °C) may be predominately ascribed to the enhanced electrochemical activity as well as electric conductivity due to the presence of FNA exsolution. The maximum power densities (P max s) of a single cell with the composite anode achieve 0.74, 0.58, 0.40, and 0.25 W cm −2 at 800, 750, 700 and 650 °C, respectively, which is comparable to the performance of Fe Ni-SDC cermets anode. However, the long time stability of the composite anode is superior to that of the Fe Ni-SDC cermets in various fuels, suggesting that SLF-FNA is sulfur-tolerant and coking-tolerant composite anode material, which possess great potentials for future application. The results can be used as guidance for designing high-performance composite anodes for intermediate temperature solid oxide fuel cells (IT-SOFCs). [ABSTRACT FROM AUTHOR]