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Fast and complete degradation of norfloxacin by using Fe/Fe3C@NG as a bifunctional catalyst for activating peroxymonosulfate.
- Source :
-
Separation & Purification Technology . Aug2018, Vol. 202, p307-317. 11p. - Publication Year :
- 2018
-
Abstract
- A composite of Fe/Fe 3 C and N-doped graphitic carbon (Fe/Fe 3 C@NG) was prepared and used as a catalyst for the activation of peroxymonosulfate (PMS) toward the oxidative degradation of Norfloxacin (NOF). It was observed that Fe/Fe 3 C@NG behaved as a bifunctional material, showing both good adsorption ability and catalytic activity. The maximum adsorption capacity of Fe/Fe 3 C@NG for NOF was evaluated as 0.13 mmol g −1 . Under given conditions (NOF concentration 0.1 mmol L −1 , catalyst load 0.1 g L −1 and PMS addition 1 mmol L −1 ), the degradation of NOF was almost completely achieved in 20 min with a degradation rate constant of 0.22 min −1 . A non-radical mechanism was proposed for the activation of PMS by Fe/Fe 3 C@NG by the scavenging test, EPR and chronoamperometry analysis. The fast and complete degradation of NOF was achieved via a rapid electron transform, in which both PMS and NOF molecular were adsorbed on the surface of Fe/Fe 3 C@NG and PMS was activated by obtaining electrons from NOF to oxidize NOF. The present study provides a green bifunctional catalyst for the oxidative removal of organic pollutants in various environmental media. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 13835866
- Volume :
- 202
- Database :
- Academic Search Index
- Journal :
- Separation & Purification Technology
- Publication Type :
- Academic Journal
- Accession number :
- 129680372
- Full Text :
- https://doi.org/10.1016/j.seppur.2018.03.049