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Palladium-Catalyzed Decarbonylative Alkynylation of Amides.
- Source :
-
Organic Letters . 5/4/2018, Vol. 20 Issue 9, p2741-2744. 4p. - Publication Year :
- 2018
-
Abstract
- A palladium-catalyzed decarbonylative alkynylation of amides via C-N bond activation is developed. Compared with the reported Ni/Cu catalyzed reaction, which only proceeded well with silylacetylenes, this transformation was also applicable to both aromatic and aliphatic terminal alkynes, including those bearing functional groups, and thus provided a general and straightforward access to diverse internal alkynes. [ABSTRACT FROM AUTHOR]
- Subjects :
- *PALLADIUM catalysts
*DECARBONYLATION
*AMIDES
*NICKEL catalysts
*CHEMICAL bonds
Subjects
Details
- Language :
- English
- ISSN :
- 15237060
- Volume :
- 20
- Issue :
- 9
- Database :
- Academic Search Index
- Journal :
- Organic Letters
- Publication Type :
- Academic Journal
- Accession number :
- 129578946
- Full Text :
- https://doi.org/10.1021/acs.orglett.8b00949