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A double-chamber energy storage device with dual ionic electrolyte enabling high energy density.
- Source :
-
Electrochimica Acta . Jun2018, Vol. 274, p31-39. 9p. - Publication Year :
- 2018
-
Abstract
- In this work, for the first time, we design a high-energy-density double-chamber capacitor which consists of the cathode chamber (polyaniline@carbon fiber cloth electrode in HCl/FeCl 3 solution), anion-exchange membrane and the anode chamber (polyaniline@carbon fiber cloth electrode in HCl/FeCl 2 solution). Since the redox state of polyaniline can be continuously altered by the external potential during charging and discharging process, the addition of FeCl 3 (or FeCl 2 ) in the electrolyte works as chemical oxidant (or reductant) to oxidize (or reduce) the reduced (or oxidized) polyaniline to offer extended capacitance. Results show the double-chamber supercapacitor has a high area specific capacitance of 1.22 F cm −2 and an energy density of 108.44 μWh cm −2 , which are ∼3.5 times as large as those of the conventional single-chamber capacitor (0.35 F cm −2 / 31.11 μWh cm −2 ). This work demonstrates an innovative strategy by incorporating supercapacitor with fuel cell to improve the energy density. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 00134686
- Volume :
- 274
- Database :
- Academic Search Index
- Journal :
- Electrochimica Acta
- Publication Type :
- Academic Journal
- Accession number :
- 129449600
- Full Text :
- https://doi.org/10.1016/j.electacta.2018.04.085