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Synthesis and Evaluation of O³-Derived Diazeniumdiolates Activatable via Bioorthogonal Chemistry Reactions in Living Cells.

Authors :
Tian Lv
Jianbing Wu
Fenghua Kang
Tingting Wang
Boheng Wan
Jin-Jian Lu
Yihua Zhang
Zhangjian Huang
Source :
Organic Letters. 4/20/2018, Vol. 20 Issue 8, p2164-2167. 4p.
Publication Year :
2018

Abstract

A class of O²-alkyl derived diazeniumdiolates 3a-f and 4a-c were designed and synthesized as new bioorthogonal NO precursors, which can be effectively uncaged in the presence of a palladium catalyst via bioorthogonal bond cleavage reactions to generate NO in living cancer cells, eliciting potent antiproliferative activity. [ABSTRACT FROM AUTHOR]

Details

Language :
English
ISSN :
15237060
Volume :
20
Issue :
8
Database :
Academic Search Index
Journal :
Organic Letters
Publication Type :
Academic Journal
Accession number :
129347735
Full Text :
https://doi.org/10.1021/acs.orglett.8b00423