Mechanistic investigation of the formation of H2 from HCOOH with a dinuclear Ru model complex for formate hydrogen lyase.

Authors :: Taisuke Tokunaga
Takeshi Yatabe
Takahiro Matsumoto
Tatsuya Ando
Ki-Seok Yoon
Seiji Ogo
Source :: Science & Technology of Advanced Materials. 2017 NGR1, Vol. 18, p870-876. 7p.
Publication Year :: 2017
Abstract: We report the mechanistic investigation of catalytic H2 evolution from formic acid in water using a formate-bridged dinuclear Ru complex as a formate hydrogen lyase model. The mechanistic study is based on isotope-labeling experiments involving hydrogen isotope exchange reaction. [ABSTRACT FROM AUTHOR]

Full Text Access

Tools