Morphology-Driven Emissivity of Microscale Tree-like Structures for Radiative Thermal Management.

Spectral emissivity of surface materials has a strong impact on thermal properties of systems that are exposed in the ambient environment. While the solar spectrum heating up the surface ranges from 200 to 2,500 nm, the atmospheric transmission spectrum allowed for infrared cooling ranges from 8 to 14 µm. However, conventional surface materials have emissivity values that are either high or low throughout the spectrum. For example, ceramic materials are typically emissive and metallic materials are typically reflective and not emissive. Here, we show that surface materials with artificial periodicities can have a selectively controlled emissivity and that the surface morphology can transform ceramic materials to be reflective or metallic materials to be emissive. As a model system, we use microscale tree-like structures, or briefly micro-trees, to demonstrate wide variations of morphology-driven emissivity spectra. Our computation based on the rigorous coupled-wave analysis shows that optimal designs of micro-trees can act as a nearly perfect reflector or a black body depending on the spectral range and offer radiative cooling or heating capabilities beyond the limits of conventional materials. For cooling, metallic micro-trees provide a surface temperature 10 K lower than that of bare metallic surfaces in a normal ambient condition, and for heating, ceramic micro-trees provide a surface temperature 8 K higher than that of bare ceramic materials. The morphology-driven emissivity of micro-trees can offer a net cooling power of 136 W/m2 or a net heating power of 12 W/m2 depending on the application without requiring any active devices, and these results guide optimal designs of artificial materials for thermal management. [ABSTRACT FROM AUTHOR]