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Van't Hoff analysis in chiral chromatography.

Authors :
Asnin, Leonid D.
Stepanova, Maria V.
Source :
Journal of Separation Science. Mar2018, Vol. 41 Issue 6, p1319-1337. 19p.
Publication Year :
2018

Abstract

Abstract: The present review discusses the theory and application of van't Hoff analysis in chiral chromatography, with main focus on liquid chromatography. The topics considered include the physical meaning of van't Hoff equation's parameters, interpretation of thermodynamic data in terms of retention and enantioseparation mechanisms, abnormal behavior of van't Hoff plots, and best practices to avoid biased results. [ABSTRACT FROM AUTHOR]

Details

Language :
English
ISSN :
16159306
Volume :
41
Issue :
6
Database :
Academic Search Index
Journal :
Journal of Separation Science
Publication Type :
Academic Journal
Accession number :
128817971
Full Text :
https://doi.org/10.1002/jssc.201701264