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Rhodium-catalyzed NH-indole-directed ortho C[sbnd]H coupling of 2-arylindoles with diazo compounds via metal carbene migratory insertion.

Authors :
Guo, Xiemin
Han, Qingshuai
Tang, Ziyuan
Su, Lv
Zhang, Xinyu
Zhang, Xiaofeng
Lin, Shen
Huang, Qiufeng
Source :
Tetrahedron Letters: International Organ for the Rapid Publication of Preliminary Communications in Organic Chemistry. Apr2018, Vol. 59 Issue 16, p1568-1572. 5p.
Publication Year :
2018

Abstract

A high regioselective rhodium-catalyzed ortho C H coupling of 2-arylindoles with diazo compounds via NH-indole-directed C H bond activation has been developed. The catalytic reaction features mild reaction conditions, broad substrate scope and good functional group tolerability. [ABSTRACT FROM AUTHOR]

Details

Language :
English
ISSN :
00404039
Volume :
59
Issue :
16
Database :
Academic Search Index
Journal :
Tetrahedron Letters: International Organ for the Rapid Publication of Preliminary Communications in Organic Chemistry
Publication Type :
Academic Journal
Accession number :
128787348
Full Text :
https://doi.org/10.1016/j.tetlet.2018.03.027