Finite element method for coupled diffusion-deformation theory in polymeric gel based on slip-link model.

A polymeric gel is an aggregate of polymers and solvent molecules, which can retain its shape after a large deformation. The deformation behavior of polymeric gels was often described based on the Flory-Rehner free energy function without considering the influence of chain entanglements on the mechanical behavior of gels. In this paper, a new hybrid free energy function for gels is formulated by combining the Edwards-Vilgis slip-link model and the Flory-Huggins mixing model to quantify the time-dependent concurrent process of large deformation and mass transport. The finite element method is developed to analyze examples of swelling-induced deformation. Simulation results are compared with available experimental data and show good agreement. The influence of entanglements on the time-dependent deformation behavior of gels is also demonstrated. The study of large deformation kinetics of polymeric gel is useful for diverse applications. [ABSTRACT FROM AUTHOR]