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Manufacturing of γ-LiAlO2 matrix for molten carbonate fuel cell by high-energy milling.
- Source :
-
International Journal of Hydrogen Energy . Mar2018, Vol. 43 Issue 13, p6696-6700. 5p. - Publication Year :
- 2018
-
Abstract
- Molten carbonate fuel cells (MCFCs) are promising high temperature power generating devices. However, unlike solid oxide fuel cells (SOFCs) they utilize a liquid electrolyte which must be immobilized in a porous matrix. In this paper, a slurry composition for lithium aluminate ( γ -LiAlO 2 ) matrix was developed and green matrices were subsequently formed by the tape casting method. In order to achieve the desired structure of the matrix (pore size, porosity) γ -LiAlO 2 powder was milled in a planetary ball mill for 18 h with a solvent, dispersant and defoamer. After this step, other ingredients were added, including a binder and plasticizer to obtain optimal rheology of the slurry. Cell tests confirmed optimal performance of the matrix compared to the third party reference γ -LiAlO 2 matrices. Burned out matrix was characterized by scanning electron microscopy (SEM) and laser diffraction in order to determine the γ -LiAlO 2 powder particle size and morphology. The results show that high-energy milling enabled a fine pore structure and high specific surface area of the matrix to be obtained in a relatively short time, compared to conventional fabrication routes. The matrix structure obtained within this study is suitable for high performance operation of MCFC. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 03603199
- Volume :
- 43
- Issue :
- 13
- Database :
- Academic Search Index
- Journal :
- International Journal of Hydrogen Energy
- Publication Type :
- Academic Journal
- Accession number :
- 128518874
- Full Text :
- https://doi.org/10.1016/j.ijhydene.2018.02.085