Back to Search
Start Over
Synthesis of Nanostructured PbO@C Composite Derived from Spent Lead-Acid Battery for Next-Generation Lead-Carbon Battery.
- Source :
-
Advanced Functional Materials . 2/28/2018, Vol. 28 Issue 9, p1-9. 9p. - Publication Year :
- 2018
-
Abstract
- Lead-carbon batteries could provide better performance on high-rate partial-state-of-charge (HRPSoC) cycles than lead-acid batteries (LABs), making them promising for the new-generation of hybrid electric vehicles. The addition of carbon allotropes to the negative active material (NAM) could induce a significant improvement to the battery performance. Herein, an environmentally friendly strategy is demonstrated to prepare lead oxide and carbon (PbO@C) composite by pyrolyzing the lead citrate precursor derived from the spent lead paste of LABs. When the PbO@C composite is used as an additive to the NAM of lead-carbon batteries, the utilization efficiency of the NAM is improved from 56.9% to 72.5%, and the cycle life of the cell in HRPSoC is tremendously extended by four times compared with the control one. The enhancement in battery performance is attributed to the hydrophilic carbon in the composite, which acts as a 3D electroosmotic pump facilitating electrolyte diffusion, and hindering the tendency to excess sulfation during the HRPSoC operation. This proposed research provides a sustainable and scalable strategy to recycle the discarded/spent LABs into high-performance lead-carbon batteries. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 1616301X
- Volume :
- 28
- Issue :
- 9
- Database :
- Academic Search Index
- Journal :
- Advanced Functional Materials
- Publication Type :
- Academic Journal
- Accession number :
- 128373156
- Full Text :
- https://doi.org/10.1002/adfm.201705294