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Ruthenium-Catalyzed Hydrogenation of Carbocyclic Aromatic Amines: Access to Chiral Exocyclic Amines.

Authors :
Zhong Yan
Huan-Ping Xie
Hong-Qiang Shen
Yong-Gui Zhou
Source :
Organic Letters. 2/16/2018, Vol. 20 Issue 4, p1094-1097. 4p.
Publication Year :
2018

Abstract

The first highly enantioselective hydrogenation of carbocyclic aromatic amines has been successfully realized using in situ-generated chiral ruthenium complex as catalyst, affording facile access to chiral exocyclic amines with up to 98% ee. [ABSTRACT FROM AUTHOR]

Details

Language :
English
ISSN :
15237060
Volume :
20
Issue :
4
Database :
Academic Search Index
Journal :
Organic Letters
Publication Type :
Academic Journal
Accession number :
128151363
Full Text :
https://doi.org/10.1021/acs.orglett.7b04060