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Surfactant assisted, one-step synthesis of Fe3O4 nanospheres and further modified Fe3O4/C with excellent lithium storage performance.
- Source :
-
Journal of Electroanalytical Chemistry . Feb2018, Vol. 810, p248-254. 7p. - Publication Year :
- 2018
-
Abstract
- Fe 3 O 4 nanospheres are synthesized by a solvothermal method with only one step under the assistance of surfactant. Fe 3 O 4 /C nanospheres are further fabricated by modifying Fe 3 O 4 nanospheres with glucose as carbon source. The crystalline structure and surface morphology are investigated by a combination of X-ray diffraction, Roman spectroscopy, transmission electron microscopy and scanning electron microscopy. The results suggest that cubic Fe 3 O 4 nanospheres are achieved, with a diameter around 200 nm. After the coating process, uniform carbon layer ~5 nm is formed on the surface of Fe 3 O 4 spheres. The electrochemical performances of prepared Fe 3 O 4 and Fe 3 O 4 /C nanospheres as anode materials for lithium-ion batteries are conducted via galvanostatic discharge/charge measurements and cyclic voltammetry. Under a current density of 100 mA g −1 , the Fe 3 O 4 /C nanospheres exhibit a delithiation capacity of 767.2 mAh g −1 over 100 cycles with excellent capacity retention of 98.2% and improved rate capacities, both of which are better than those of Fe 3 O 4 nanospheres. This work demonstrates that the prepared Fe 3 O 4 /C nanospheres can be a promising anode material for lithium ion batteries. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 15726657
- Volume :
- 810
- Database :
- Academic Search Index
- Journal :
- Journal of Electroanalytical Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 127982352
- Full Text :
- https://doi.org/10.1016/j.jelechem.2018.01.025