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Enhancement of breakdown electric field and DC bias of (In0.5Nb0.5)0.005(Ti1-xZrx)0.995O2 colossal permittivity ceramics.
- Source :
-
Journal of Alloys & Compounds . Apr2018, Vol. 740, p1108-1115. 8p. - Publication Year :
- 2018
-
Abstract
- In, Nb, and Zr co-doped TiO 2 ((In 0.5 Nb 0.5 ) 0.005 (Ti 1-x Zr x ) 0.995 O 2 ) (x = 0–0.80) ceramics were prepared by a solid-state reaction method, and their structures, dielectric properties, and response to DC bias were studied. The solubility limit was found to be near x = 0.10, and the excess added Zr was present in the form of secondary ZrTiO 4 phase. The mean grain size increased from 20.2 to 39.5 μm in the x = 0–0.10 range and then decreased to 5.2 μm for x = 0.20. Permittivity at 1 kHz exceeded 10 4 for the samples in the x = 0–0.20 range and then decreased to 570 for x = 0.40. For x = 0.20, the ceramic sample showed ε r ≈ 10 4 and tanδ ≤ 0.05 (20 Hz–100 kHz), as well as good temperature (−150 to 125 °C) and DC bias (0–875 v/cm) stability. The breakdown electric field increased from 940 v/cm for x = 0 to 5770 v/cm for x = 0.20. The excellent dielectric properties are attributed to the coexistence of smaller grains and the presence of insulating ZrTiO 4 in the sample. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 09258388
- Volume :
- 740
- Database :
- Academic Search Index
- Journal :
- Journal of Alloys & Compounds
- Publication Type :
- Academic Journal
- Accession number :
- 127982284
- Full Text :
- https://doi.org/10.1016/j.jallcom.2018.01.052