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New addition and cyclization reactions involving phosphorus based allenes.
- Source :
-
Phosphorus, Sulfur & Silicon & the Related Elements . 2018, Vol. 193 Issue 2, p81-87. 7p. - Publication Year :
- 2018
-
Abstract
- In this paper, we describe convenient methods for functionally active phenol addition reaction of allenylphosphonates/allenyl phosphine oxides. These reactions lead to either vinyl or allylphosphonates. In the reaction α-aryl allenylphosphonates with 2-iodophenol in the presence of Pd nanoparticles [Pd-PVP] isomeric vinylphosphonates are preferentially obtained. A novel cyclization reaction of 2-iodo-t-butylbenzaldimine with and allenylphosphine oxide that leads to an isoquinoline is also discovered; the product is characterized by single crystal X-ray structure determination. [ABSTRACT FROM PUBLISHER]
Details
- Language :
- English
- ISSN :
- 10426507
- Volume :
- 193
- Issue :
- 2
- Database :
- Academic Search Index
- Journal :
- Phosphorus, Sulfur & Silicon & the Related Elements
- Publication Type :
- Academic Journal
- Accession number :
- 127784972
- Full Text :
- https://doi.org/10.1080/10426507.2017.1417302