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Supercritical diethylamine facilitated loading of ultrafine Ru particles on few-layer graphene for solvent-free hydrogenation of levulinic acid to γ-valerolactone.
- Source :
-
Nanotechnology . 2/16/2018, Vol. 29 Issue 7, p1-1. 1p. - Publication Year :
- 2018
-
Abstract
- We demonstrate a facile and versatile method to grow Ru particles uniformly on pristine few-layer graphene (FLG) in supercritical diethylamine. In particular, a large number of Ru subnanometer clusters less than 1.0 nm were observed. The particle size can be tuned by manipulating the loading content of Ru and controlling the reaction temperature. The resulting Ru/FLG showed remarkably high activity, selectivity, and reusability towards the hydrogenation of levulinic acid to γ-valerolactone. This method is flexible, and can be extended to the synthesis of a variety of other ultrafine metal particles supported on FLG. [ABSTRACT FROM AUTHOR]
- Subjects :
- *DIETHYLAMINE
*HYDROGENATION
*GRAPHENE
Subjects
Details
- Language :
- English
- ISSN :
- 09574484
- Volume :
- 29
- Issue :
- 7
- Database :
- Academic Search Index
- Journal :
- Nanotechnology
- Publication Type :
- Academic Journal
- Accession number :
- 127332802
- Full Text :
- https://doi.org/10.1088/1361-6528/aa9b70