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Aminomethylation of Fullerene C60 with N,N',N"-Triaryl- or N,N',N"-Trihetaryl-1,3,5-perhydrotriazines in the Presence of EtMgBr and Ti(Oi-Pr)4.
- Source :
-
Journal of Organic Chemistry . 1/5/2018, Vol. 83 Issue 1, p459-462. 4p. - Publication Year :
- 2018
-
Abstract
- A new method for the functionalization of fullerenes based on the reaction between in situ generated aryl- or hetaryl-containing 1,3,5-perhydrotriazines and EtMgBr in the presence of Ti(Oi-Pr)4 has been developed. The cleavage of the triazine ring under previously developed conditions1-6 results in the formation of aminomethylated derivatives of fullerene C60 with high yields (80-90%) and selectivity (~90%). [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 00223263
- Volume :
- 83
- Issue :
- 1
- Database :
- Academic Search Index
- Journal :
- Journal of Organic Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 127281063
- Full Text :
- https://doi.org/10.1021/acs.joc.7b02526