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Solubility of salts of d-elements in organic and water-organic solvents: V. Inner-sphere chalcogen S-S contacts in the [Ni(DMSO)(HO)]Cl solvate.
- Source :
-
Russian Journal of General Chemistry . Nov2017, Vol. 87 Issue 11, p2748-2749. 2p. 1 Diagram. - Publication Year :
- 2017
-
Abstract
- It was proved by the IR spectroscopy that the first coordination sphere of nickel cations in the NiCl·2DMSO·9HO, NiCl·5DMSO·4HO, and NiCl·4DMSO·2HO compounds contains dimethyl sulfoxide and water ligands. According to X-ray structural analysis, in crystals of the NiCl·4DMSO·2HO compound, noncovalent contacts between sulfur atoms of neighboring dimethyl sulfoxide molecules are realized in the inner sphere of the complex. [ABSTRACT FROM AUTHOR]
- Subjects :
- *ORGANIC solvents
*SALTS
*SOLUBILITY
Subjects
Details
- Language :
- English
- ISSN :
- 10703632
- Volume :
- 87
- Issue :
- 11
- Database :
- Academic Search Index
- Journal :
- Russian Journal of General Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 126766790
- Full Text :
- https://doi.org/10.1134/S1070363217110378