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Crystal structures of salen-type ligands 2-[(1E)-({1-(3-chlorophenyl)-2-[(E)-(2-hydroxybenzylidene)amino]propyl}imino)methyl]phenol and 2-[(1E)-({1-(4-chlorophenyl)-2-[(E)-(2-hydroxybenzylidene)amino]propyl}imino)methyl]phenol.
- Source :
-
Acta Crystallographica Section E: Crystallographic Communications . Dec2017, Vol. 73 Issue 12, p1878-1881. 14p. - Publication Year :
- 2017
-
Abstract
- The title compounds, C23H21ClN2O2, differ from each other only by the position of the Cl atom on the corresponding benzene ring: meta relative to the central sp3 C atom for (I) and para for (II). In (I), the hy­droxy­phenyl rings are almost parallel, the dihedral angle between the mean planes being 9.2 (2)°, but in (II), the relative position of the ring is different, characterized by a dihedral angle of 48.5 (1)°. Compound (I) features intra­molecular O—H···N and inter­molecular C—H···O hydrogen bonds, while in (II), intra­molecular O—H···N, C—H···N hydrogen bonds and weak inter­molecular C—H···π inter­actions are observed. Compound (I) was refined as an inversion twin. [ABSTRACT FROM AUTHOR]
- Subjects :
- *CRYSTAL structure
*LIGAND crystallography
*INTRAMOLECULAR forces
Subjects
Details
- Language :
- English
- ISSN :
- 20569890
- Volume :
- 73
- Issue :
- 12
- Database :
- Academic Search Index
- Journal :
- Acta Crystallographica Section E: Crystallographic Communications
- Publication Type :
- Academic Journal
- Accession number :
- 126700812
- Full Text :
- https://doi.org/10.1107/S2056989017016292