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Mild Decarboxylative C−H Alkylation: Computational Insights for Solvent-Robust Ruthenium(II) Domino Manifold.

Authors :
Kumar, N. Y. Phani
Rogge, Torben
Yetra, Santhivardhana Reddy
Bechtoldt, Alexander
Clot, Eric
Ackermann, Lutz
Source :
Chemistry - A European Journal. 12/11/2017, Vol. 23 Issue 69, p17449-17453. 5p.
Publication Year :
2017

Abstract

Computational studies on decarboxylative C−H alkenylations provided key insights into the solvent-robust nature of C−H activation/decarboxylation domino reactions. These properties were exploited for ruthenium(II)-catalyzed C−H alkylations by a decarboxylative process with ample scope under copper-free and silver-free reaction conditions. [ABSTRACT FROM AUTHOR]

Details

Language :
English
ISSN :
09476539
Volume :
23
Issue :
69
Database :
Academic Search Index
Journal :
Chemistry - A European Journal
Publication Type :
Academic Journal
Accession number :
126686103
Full Text :
https://doi.org/10.1002/chem.201703680