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A New Insulin-Like Vanadyl Complex: Synthesis and Structure of V(IV)O(H 2 O) 2 (2,6-PyridineDicarboxylate) E 2H 2 O.
- Source :
-
Journal of Coordination Chemistry . 1/20/2004, Vol. 57 Issue 2, p157-165. 9p. 3 Diagrams, 7 Charts. - Publication Year :
- 2004
-
Abstract
- V(IV)O(H 2 O) 2 (2,6-pyridinedicarboxylate)·2H 2 O ( 1 ) was obtained by the reaction of VO(acac) 2 with 2,6-pyridine dicarboxylic acid in MeOH and water. Complex ( 1 ) was characterized by IR spectroscopy, element analysis and X-ray diffraction. It crystallizes in space group P . X-ray structure analysis has shown that complex ( 1 ) is a monomeric neutral complex containing vanadyl ion, 2,6-pyridinedicarboxylate ligand and coordinated water, possessing distorted octahedral geometry. Complex ( 1 ) is constructed from mononuclear vanadium, V(IV)O(H 2 O) 2 (2,6-pyridinedicarboxylate) units and crystallization water molecules held together in an extensive two-dimensional network via O-H···O hydrogen bonds, π-π stacking interactions between parallel aromatic pyridines, and face-to-face stacking interactions between parallel carbonyl groups of 2,6-pyridine dicarboxylic acid ligands along the plane formed by the x , z axis of the unit cell. [ABSTRACT FROM AUTHOR]
- Subjects :
- *CHEMICAL reactions
*INFRARED spectroscopy
*X-ray diffraction
*IONS
*PYRIDINE
Subjects
Details
- Language :
- English
- ISSN :
- 00958972
- Volume :
- 57
- Issue :
- 2
- Database :
- Academic Search Index
- Journal :
- Journal of Coordination Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 12660810
- Full Text :
- https://doi.org/10.1080/00958970410001666161