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The synthesis of 1 × 1 magnesium octahedral molecular sieve with controllable size and shape for aqueous magnesium ion battery cathode material.
- Source :
-
Journal of Electroanalytical Chemistry . Dec2017, Vol. 807, p37-44. 8p. - Publication Year :
- 2017
-
Abstract
- The 1 × 1 magnesium octahedral molecular sieve (Mg-OMS-7), utilizing as cathode material in aqueous rechargeable magnesium ions batteries, is synthesized by a simple one-step hydrothermal method. Meanwhile, by changing the concentrations of H 2 SO 4 , the Mg-OMS-7 materials with controllable size and shape are obtained. To check the structure and morphology, the host materials are measured by X-ray power diffraction, scanning, transmission and high-resolution transmission electron microscopy. The electrochemical reaction mechanism is examined by cyclic voltammetry and X-ray photoelectron spectroscopy. The Mg-OMS-7 changes the morphology from micro-rugby to nano-club by controlling the concentrations of H 2 SO 4 . The nano-club Mg-OMS-7 which obtained by the 1.6 mol dm − 3 H 2 SO 4 owns a more uniformly distribution and smaller size, which provides the shorter route for magnesium ions insert/deinsert into/from the lattice of host material and exhibits the better rate ability and cycle performance. The initial discharge capacity of this electrode can obtain 283.1 mAh g − 1 at the current density of 10 mA g − 1 in the 0.2 mol dm − 3 Mg(NO 3 ) 2 aqueous electrolyte and the specific capacity retention rate is 94.1% after cycling 200 cycles at 100 mA g − 1 in the 0.5 mol dm − 3 Mg(NO 3 ) 2 electrolyte. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 15726657
- Volume :
- 807
- Database :
- Academic Search Index
- Journal :
- Journal of Electroanalytical Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 126478842
- Full Text :
- https://doi.org/10.1016/j.jelechem.2017.10.065