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Rhodium-catalyzed carbonylation of 2-alkynylbenzylamine: a new route to the synthesis of benzazepinones

Authors :
Shiba, Takanori
Zhou, Da-Yang
Onitsuka, Kiyotaka
Takahashi, Shigetoshi
Source :
Tetrahedron Letters: International Organ for the Rapid Publication of Preliminary Communications in Organic Chemistry. Apr2004, Vol. 45 Issue 16, p3211. 3p.
Publication Year :
2004

Abstract

Rhodium-catalyzed carbonylation of 2-alkynylbenzylamines under water–gas shift reaction conditions gives a seven-membered heterocyclic product, 2,4-disubstituted-1,4-dihydrobenz[<f>c</f>]azepin-3-ones, in a good yield. [Copyright &y& Elsevier]

Details

Language :
English
ISSN :
00404039
Volume :
45
Issue :
16
Database :
Academic Search Index
Journal :
Tetrahedron Letters: International Organ for the Rapid Publication of Preliminary Communications in Organic Chemistry
Publication Type :
Academic Journal
Accession number :
12639786
Full Text :
https://doi.org/10.1016/j.tetlet.2004.02.122