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Durability improving and corrosion-resistance mechanism of graphene oxide modified ultra-thin carbon paper used in PEM fuel cell.

Authors :
Yang, Piaopiao
Wu, Xiaobo
Xie, Zhiyong
Wang, Pan
Liu, Chunbo
Huang, Qizhong
Source :
Corrosion Science. Jan2018, Vol. 130, p95-102. 8p.
Publication Year :
2018

Abstract

The corrosion-resistance properties of modified ultra-thin carbon paper (CP) different graphene oxide (GO) content used in proton exchange membrane fuel cells (PEMFC) are studied for the first time. Results show that CP with 1 wt% GO has distinguished corrosion-resistance property (corrosion current: 5.539E − 8A.cm −2 , minimum weight loss and contact angle variation). And mechanism analysis was found that the CP-1GO-P had uniform florine coating on some area of carbon fiber while T-CP-P has little. Moreover, the addition of GO could introduce more C O and C O groups which interact with the florine atom, thus can strengthen the bonding of PTFE and matrix carbon effectively. [ABSTRACT FROM AUTHOR]

Details

Language :
English
ISSN :
0010938X
Volume :
130
Database :
Academic Search Index
Journal :
Corrosion Science
Publication Type :
Academic Journal
Accession number :
126296680
Full Text :
https://doi.org/10.1016/j.corsci.2017.10.025