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Front Cover: Stereospecific Winding of Polycyclic Aromatic Hydrocarbons into Trinacria Propellers (Chem. Eur. J. 61/2017).
- Source :
-
Chemistry - A European Journal . 11/2/2017, Vol. 23 Issue 61, p15233-15233. 1p. - Publication Year :
- 2017
-
Abstract
- The synthesis of molecular propellers featuring low ‐ energy activation barriers of the racemization reaction remains elusive. The trimerization reaction of enantiomerically ‐ pure binaphthols with hexakis(bromomethyl)benzene enabled the one ‐ step preparation of enantiomerically ‐ pure molecular propellers, in which three binaphthyl rings are held together through dioxecine rings. X ‐ ray diffraction analysis revealed that the six naphthyl moieties adopt a folded conformation, which shows a striking similarity to the mythological Sicilian symbol of Trinacria. More information can be found in the Full Paper by D. Bonifazi et al. on page 15348. [ABSTRACT FROM AUTHOR]
- Subjects :
- *AROMATIC compounds
*HYDROCARBONS
Subjects
Details
- Language :
- English
- ISSN :
- 09476539
- Volume :
- 23
- Issue :
- 61
- Database :
- Academic Search Index
- Journal :
- Chemistry - A European Journal
- Publication Type :
- Academic Journal
- Accession number :
- 126015813
- Full Text :
- https://doi.org/10.1002/chem.201703995