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Front Cover: Stereospecific Winding of Polycyclic Aromatic Hydrocarbons into Trinacria Propellers (Chem. Eur. J. 61/2017).

Authors :
Mosca, Dario
Stopin, Antoine
Wouters, Johan
Demitri, Nicola
Bonifazi, Davide
Source :
Chemistry - A European Journal. 11/2/2017, Vol. 23 Issue 61, p15233-15233. 1p.
Publication Year :
2017

Abstract

The synthesis of molecular propellers featuring low ‐ energy activation barriers of the racemization reaction remains elusive. The trimerization reaction of enantiomerically ‐ pure binaphthols with hexakis(bromomethyl)benzene enabled the one ‐ step preparation of enantiomerically ‐ pure molecular propellers, in which three binaphthyl rings are held together through dioxecine rings. X ‐ ray diffraction analysis revealed that the six naphthyl moieties adopt a folded conformation, which shows a striking similarity to the mythological Sicilian symbol of Trinacria. More information can be found in the Full Paper by D. Bonifazi et al. on page 15348. [ABSTRACT FROM AUTHOR]

Subjects

Subjects :
*AROMATIC compounds
*HYDROCARBONS

Details

Language :
English
ISSN :
09476539
Volume :
23
Issue :
61
Database :
Academic Search Index
Journal :
Chemistry - A European Journal
Publication Type :
Academic Journal
Accession number :
126015813
Full Text :
https://doi.org/10.1002/chem.201703995