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Fabrication of multilayered-sandwich MoS2/c architectures with advanced lithium storage properties.

Authors :
Du, Jinlong
Yang, Zhanxu
Wang, Xiaorong
Qi, Chengyuan
Li, Yue
Mao, Wei
Qiao, Haiyan
Yu, ZongBao
Ren, Tieqiang
Qiao, Qingdong
Source :
Electrochimica Acta. Oct2017, Vol. 250, p238-243. 6p.
Publication Year :
2017

Abstract

MoS 2 /C nanocomposite with a multilayered sandwich structure based on few-layered MoS 2 and carbon layers in an alternating sequence, was successfully synthesized through a one-step synchronized carbonization and sulfuration method. The hybrids were characterized by X-ray diffraction, High-resolution transmission electron microscopy, Atomic force microscope, Raman and X-ray photoelectron spectroscopic methods. The as-obtained MoS 2 /C nanocomposite applied as lithium-ion batteries anode materials, showed a high initial discharge and charge capacities of 1678.5 and 1386.0 mAh g −1 , respectively. High specific reversible capacity is maintained at fast C rates, e.g., 1390, 1223, 1017, 566, and 450 mAh g −1 at 0.1C, 0.6C, 3C, 10C and 20C, respectively. The good performance of the composite is mainly attributed to the unique few layered composite architectures, which can improve ion/electron transportation and prevent aggregation and restacking during the lithiation/delithiation process. [ABSTRACT FROM AUTHOR]

Details

Language :
English
ISSN :
00134686
Volume :
250
Database :
Academic Search Index
Journal :
Electrochimica Acta
Publication Type :
Academic Journal
Accession number :
125856648
Full Text :
https://doi.org/10.1016/j.electacta.2017.08.061