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Hyperbranched polyester poly[3-(morpholin-4-yl)propionates] and their copper(II) complexes.
- Source :
-
Russian Journal of General Chemistry . Sep2017, Vol. 87 Issue 9, p1995-2005. 11p. - Publication Year :
- 2017
-
Abstract
- Novel polydentate ligands on the basis of second- and third-generation hyperbranched polyesters containing terminal poly[3-(morpholin-4-yl)propionate] groups and their 6 : 1 and 13 : 1 polynuclear copper(II) complexes were synthesized. The degree of functionalization of the polyesters with morpholine increases in going from the second (56%) to third generation (68%). According to IR and electronic spectroscopy data, each coordination entity in the complexes is an isolated paramagnetic center of the formula CuNOSolv (Solv = HO, DMSO). [ABSTRACT FROM AUTHOR]
- Subjects :
- *MORPHOLINE
*COPPER
*ELECTRIC properties
*IONIZATION energy
*PROPIONATES
*POLYESTERS
Subjects
Details
- Language :
- English
- ISSN :
- 10703632
- Volume :
- 87
- Issue :
- 9
- Database :
- Academic Search Index
- Journal :
- Russian Journal of General Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 125744569
- Full Text :
- https://doi.org/10.1134/S1070363217090158