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Inclusion of a dithiadiazolyl radical in a seemingly non-porous solid.
- Source :
-
Chemical Communications . 10/21/2017, Vol. 53 Issue 82, p11310-11313. 4p. - Publication Year :
- 2017
-
Abstract
- Inclusion of the dithiadiazolyl radical PhCNSSNá¹– into the dynamically porous metallocycle [Cu2(L1)2Cl4], where L1 is the bidentate ligand 1,3-bis(imidazol-1-ylmethyl)-2,4,6-trimethylbenzene, has been achieved by gas phase diffusion. Single crystal X-ray diffraction, powder X-ray diffraction, UV-visible spectroscopy, EPR and SQUID magnetometry studies confirm inclusion of the radical into this seemingly non-porous material, and illustrate the antiferromagnetic coupling between the paramagnetic host and guest species. The radical guest is readily released by heating or by the addition of solvent (CH2Cl2). [ABSTRACT FROM AUTHOR]
- Subjects :
- *METALLACYCLES
*X-ray diffraction
*ANTIFERROMAGNETIC materials
Subjects
Details
- Language :
- English
- ISSN :
- 13597345
- Volume :
- 53
- Issue :
- 82
- Database :
- Academic Search Index
- Journal :
- Chemical Communications
- Publication Type :
- Academic Journal
- Accession number :
- 125623077
- Full Text :
- https://doi.org/10.1039/c7cc06678c