Reduced graphene oxide supporting hollow bimetallic phosphide nanoparticle hybrids for electrocatalytic oxygen evolution.

Nanohybrids with hollow CoNiP nanoparticles decorating reduced graphene oxide (h-CoNiP/rGO) are prepared by a low-temperature phosphorization method. The h-CoNiP/rGO present favorable electrocatalytic advantages toward the oxygen evolution reaction (OER) in alkaline solution, including an onset potential of 1.44 V, a low overpotential of 280 mV at a current density of 10 mA cm − 2 , a small Tafel slope of 65.2 mV dec − 1 , and pretty good durability. The use of earth-abundant elements in a high-activity OER electrocatalyst may provide an effective way of advancing the development of full water splitting. [ABSTRACT FROM AUTHOR]