Study of Ag/CeO2 catalysts for naphthalene oxidation: Balancing the oxygen availability and oxygen regeneration capacity.

A series of Ag/CeO 2 catalysts was synthesized by the incipient wetness method. Compared with Ag/Al 2 O 3 and CeO 2 catalysts, Ag/CeO 2 catalysts are more promising candidates for naphthalene oxidation, in which Ce x + act as the main active sites and are efficiently promoted by Ag species. By characterizing the solid properties and the redox ability, the mechanism of ceria catalysis by the Ag-modified catalysts was investigated. It was found that Ag species can work as an oxygen pump to enhance the oxygen availability in the ceria bulk. They also promote the oxygen regeneration capacity by the oxygen spillover effect. However, such an effect would also decrease the ability for active oxygen regeneration at higher Ag loading, which arises from the lower surface oxygen vacancy concentration. Because of the balance between these two factors, the Ag/CeO 2 catalyst with 1 wt.% Ag shows the best performance for isothermal catalytic oxidation of naphthalene. [ABSTRACT FROM AUTHOR]