Vanadium Hydroxide Cluster Ions in the Gas Phase: Bond-Forming Reactions of Doubly-Charged Negative Ions by SO2-Promoted V−O Activation.

Authors :: Troiani, Anna
Rosi, Marzio
Garzoli, Stefania
Salvitti, Chiara
de Petris, Giulia
Source :: Chemistry - A European Journal. 9/4/2017, Vol. 23 Issue 49, p11752-11756. 5p.
Publication Year :: 2017
Abstract: The gas-phase reactivity of doubly-charged vanadium hydroxides anions with SO2 has been studied by experimental and computational methods. The obtained results highlight the role of sulfur dioxide in promoting unprecedented bond-forming reactions, which produce singly-charged products by breaking the V xO y skeleton or a terminal V−O bond. [ABSTRACT FROM AUTHOR]

Subjects :: *MESITYLENE
*GAS phase reactions
*SULFUR oxides
*ACTIVATION (Chemistry)
*COMPLEX ions

Full Text Access

Tools