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Tridentate C–I…O−–N+ halogen bonds.

Authors :
Topić, Filip
Puttreddy, Rakesh
Rautiainen, J. Mikko
Tuononen, Heikki M.
Rissanen, Kari
Source :
CrystEngComm. 9/14/2017, Vol. 19 Issue 34, p4960-4963. 4p.
Publication Year :
2017

Abstract

The X-ray structures of the first co-crystals where the three oxygen lone pairs in N-oxides are fully utilized for tridentate C–I…O−–N+ halogen bonding with 1,̉-diiodoperfluoroalkanes are reported, studied computationally, and compared with the corresponding silver(i) N-oxide complexes. [ABSTRACT FROM AUTHOR]

Subjects

Subjects :
*HALOGEN compounds
*DIIODOMETHANE

Details

Language :
English
ISSN :
14668033
Volume :
19
Issue :
34
Database :
Academic Search Index
Journal :
CrystEngComm
Publication Type :
Academic Journal
Accession number :
124932523
Full Text :
https://doi.org/10.1039/c7ce01381g