Light-induced formation of nitroxyl radicals by organic Bi(V) compounds in the presence of 2-methyl-2-nitrosopropane and C-phenyl- N- tert-butylnitrone.

Authors :: Gushchin, A.
Kalistratova, O.
Maleeva, A.
Dodonov, V.
Kosov, D.
Emel'yanov, D.
Kuropatov, V.
Source :: Russian Journal of General Chemistry. Jul2017, Vol. 87 Issue 7, p1547-1549. 3p.
Publication Year :: 2017
Abstract: The organic bismuth compounds PhBi(OCCH=CHCH) and PhBi(OCEt) decompose under scattered light in the presence of spin traps (2-methyl-2-nitrosopropane and C-phenyl- N- tert-butylnitrone) in organic solvents (acetonitrile, benzene, toluene) to form adducts of phenyl radicals with the traps. [ABSTRACT FROM AUTHOR]

Subjects :: *NITROXYL
*BISMUTH compounds
*SPIN trapping (Chemistry)
*RADICALS (Chemistry)
*PHENYL compounds
*ORGANIC solvents

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