Mg-ion conducting gel polymer electrolyte membranes containing biodegradable chitosan: Preparation, structural, electrical and electrochemical properties.

A biodegradable gel polymer electrolyte system based on chitosan/magnesium trifluoromethanesulfonate/1-ethyl-3-methylimidazolium trifluoromethanesulfonate (CA/Mg (Tf) 2 /EMITf) is developed. The structure, thermal performance, mechanical properties, ionic conductivity, relaxation time, electrochemical stability and ionic transport number of the membranes are analyzed by various techniques. The ion migration mainly depends on the complexation and decomplexation of Mg 2+ with amine band (NH 2 ) in chitosan. The 90CA-10Mg (Tf) 2 system plasticized with 10% EMITf (relative to the amount of 90CA-10Mg (Tf) 2 ) is identified as the optimum one and the temperature dependence of ionic conductivity obeys the Arrhenius rule. Moreover, the relaxation time of the electrolyte is very short, being just 1.25 × 10 −6 s, and its electrochemical stability window is quite wide, being up to 4.15 V. The anodic oxidation and cathodic reduction of Mg at the Mg-electrode/electrolyte interface is facile, and the ionic transference number of this electrolyte is 0.985, indicating that it could be a potential electrolyte candidate for Mg-ion devices. [ABSTRACT FROM AUTHOR]