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Photophysics of 7-mercapto-4-methylcoumarin and derivatives: complementary fluorescence behaviour to 7-hydroxycoumarins.
- Source :
-
Photochemical & Photobiological Sciences . Aug2017, Vol. 16 Issue 8, p1284-1289. 6p. - Publication Year :
- 2017
-
Abstract
- The photophysical behaviour of 7-mercapto-4-methylcoumarin (C-SH) and derivatives has been studied in different solvents. In contrast to 7-hydroxy-4-methylcoumarin, C-SH shows poor emission, but high fluorescence when the thiol is alkylated. The origin and character of the lowest singlet states are discussed, specifically proposing that the thione-like C=S resonance form plays a key role in excited state deactivation in C-SH. [ABSTRACT FROM AUTHOR]
- Subjects :
- *METHYLCOUMARINS
*FLUORESCENCE
*CHEMICAL derivatives
*SOLVENTS
*ALKYLATION
*THIOLS
Subjects
Details
- Language :
- English
- ISSN :
- 1474905X
- Volume :
- 16
- Issue :
- 8
- Database :
- Academic Search Index
- Journal :
- Photochemical & Photobiological Sciences
- Publication Type :
- Academic Journal
- Accession number :
- 124554282
- Full Text :
- https://doi.org/10.1039/c7pp00121e