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[60]Fullerene-Based Macrocycle Ligands.
- Source :
-
Chemistry - A European Journal . 8/4/2017, Vol. 23 Issue 44, p10485-10490. 6p. - Publication Year :
- 2017
-
Abstract
- Macrocycle ligands have three or more donor sites. Selective replacement of skeleton carbon atoms by heteroatoms and vacancies in C60 could lead to various macrocycle ligands with a cage-shaped backbone. Theoretical calculations indicate that such C60-based macrocycle ligands are as stable as C60 thermodynamically according to their similar HOMO-LUMO gaps. The synthesis of these ligands is a challenging task. Nevertheless important progresses have been reported. This concept article focuses on the structures of possible C60-based macrocycle ligands and related synthetic results. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 09476539
- Volume :
- 23
- Issue :
- 44
- Database :
- Academic Search Index
- Journal :
- Chemistry - A European Journal
- Publication Type :
- Academic Journal
- Accession number :
- 124487121
- Full Text :
- https://doi.org/10.1002/chem.201701526