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Suppression of the Charge Density Wave State in Two-Dimensional 1 T-TiSe2 by Atmospheric Oxidation.
- Source :
-
Angewandte Chemie . 7/24/2017, Vol. 129 Issue 31, p9109-9113. 5p. - Publication Year :
- 2017
-
Abstract
- Two-dimensional (2D) metallic transition-metal dichalcogenides (TMDCs), such as 1 T-TiSe2, have recently emerged as unique platforms for exploring their exciting properties of superconductivity and the charge density wave (CDW). 2D 1 T-TiSe2 undergoes rapid oxidation under ambient conditions, significantly affecting its CDW phase-transition behavior. We comprehensively investigate the oxidation process of 2D TiSe2 by tracking the evolution of the chemical composition and atomic structure with various microscopic and spectroscopic techniques and reveal its unique selenium-assisting oxidation mechanism. Our findings facilitate a better understanding of the chemistry of ultrathin TMDCs crystals, introduce an effective method to passivate their surfaces with capping layers, and thus open a way to further explore the functionality of these materials toward devices. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 00448249
- Volume :
- 129
- Issue :
- 31
- Database :
- Academic Search Index
- Journal :
- Angewandte Chemie
- Publication Type :
- Academic Journal
- Accession number :
- 124204077
- Full Text :
- https://doi.org/10.1002/ange.201612605