Back to Search
Start Over
Thienylquinonoidal Porphyrins and Hexaphyrins with Singlet Diradical Ground States.
- Source :
-
Chemistry - A European Journal . 7/3/2017, Vol. 23 Issue 37, p8969-8979. 11p. - Publication Year :
- 2017
-
Abstract
- To explore stable organic diradicaloids, meso-thienylquinonoid-substituted porphyrins Pn and hexaphyrins Hn, where 'n' denotes the number of thienyl units in the meso-substituents, were synthesized. P0 was identified as a closed-shell quinonoid, whereas P1 was shown to possess significant diradical character with diradical character index ( y) of 0.99 and quite small singlet-triplet energy gap (Δ ES-T) of −0.13 kcal mol−1. P1 was certainly stable, allowing its isolation, but decomposed gradually in solution. In the hexaphyrin series, it was shown that H0 and H1 were closed-shell quinonoids, but H2 was a highly stable diradicaloid with y=0.85 and Δ ES-T of −3.72 kcal mol−1. The high stability of H2 was ascribed to effective spin delocalization over the entire conjugated network. Characteristically, H2 displays an intense absorption band in NIR region at λmax=1175 nm with molar absorption coefficient ( ϵ) of 8.81×104 mol−1 L cm−1, a narrow HOMO-LUMO gap of 0.69 eV, and nine reversible redox potential waves. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 09476539
- Volume :
- 23
- Issue :
- 37
- Database :
- Academic Search Index
- Journal :
- Chemistry - A European Journal
- Publication Type :
- Academic Journal
- Accession number :
- 123912111
- Full Text :
- https://doi.org/10.1002/chem.201701355