Organocatalytic hydroborylation promoted by N-heterocyclic olefins.

Authors :: Hering-Junghans, Christian
Watson, Ian C.
Ferguson, Michael J.
McDonald, Robert
Rivard, Eric
Source :: Dalton Transactions: An International Journal of Inorganic Chemistry. 6/14/2017, Vol. 46 Issue 22, p7150-7153. 4p.
Publication Year :: 2017
Abstract: New complexes containing N-heterocyclic vinylene-stabilized [B2H5]+ fragments were prepared, and surprisingly it was found that the precursor N-heterocyclic olefins (NHOs) could promote the mild (room temperature) catalytic hydroborylation of ketones and aldehydes. This finding represents an important addition to the burgeoning field of non-metal mediated catalysis. [ABSTRACT FROM AUTHOR]

Language :: English
ISSN :: 14779226
Volume :: 46
Issue :: 22
Database :: Academic Search Index
Journal :: Dalton Transactions: An International Journal of Inorganic Chemistry
Publication Type :: Academic Journal
Accession number :: 123452315
Full Text :: https://doi.org/10.1039/c7dt01303e