Structure and magnetic properties of Heusler alloy Co2RuSi melt-spun ribbons.

Heusler alloy Co 2 RuSi has been synthesized by melt-spinning technology successfully. Co 2 RuSi bulk sample after annealing is composed of an HCP Co-rich phase and a BCC Ru-Si phase, but melt-spinning can suppress the precipitation of the HCP phase and produce a single Co 2 RuSi Heusler phase. In the XRD pattern, it is found that Ru has a strong preference for the (A, C) sites, though it has fewer valence electrons compared with Co. This site preference is different from the case in Heusler alloys containing only 3d elements and is supported further by first-principles calculations. Melt-spun Co 2 RuSi has a M s of 2.67 μ B /f.u. at 5 K and a Tc of 491 K. An exothermic peak is observed at 871 K in the DTA curve, corresponding to the decomposition of the Heusler phase. Finally, the site preference and magnetic properties of Co 2 RuSi were discussed based on electronic structure calculation and charge density difference. [ABSTRACT FROM AUTHOR]