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Calorimetric study of the molecular complex formation of glycyl-glycyl-glycine with 18-crown-6 in aqueous organic solvents.
- Source :
-
Russian Journal of General Chemistry . Mar2017, Vol. 87 Issue 3, p591-599. 9p. - Publication Year :
- 2017
-
Abstract
- The influence of water-ethanol (HO-EtOH), water-acetone (HO-MeAc) and waterdimethylsulfoxide (HO-DMSO) solvents on the reaction of the molecular complex formation between ether 18-crown-6 (18C6) and small peptide glycyl-glycyl-glycine (3Gly) has been studied at T = 298.15 K. The thermodynamic parameters for the reaction (log K, Δ G, Δ H, Δ S) were obtained from calorimetric titration experiments carried out by means of the calorimetric system TAM III (TA Instruments, USA). The thermodynamics of the [3Gly18C6] molecular complex formation is discussed in comparison with thermodynamic parameters of complex formation between 18C6 and amino acids in mixed solvents using the sоlvation-thermodynamic approach. [ABSTRACT FROM AUTHOR]
- Subjects :
- *SOLVENTS
*ETHANOL
*WATER
*ACETONE
*MOLECULAR structure
*SOLUTION (Chemistry)
Subjects
Details
- Language :
- English
- ISSN :
- 10703632
- Volume :
- 87
- Issue :
- 3
- Database :
- Academic Search Index
- Journal :
- Russian Journal of General Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 122685225
- Full Text :
- https://doi.org/10.1134/S1070363217030355