Development of Bi2W1−xMoxO6/Montmorillonite nanocomposite as efficient catalyst for photocatalytic desulfurization.

A novel Bi 2 W 1−x Mo x O 6 /Montmorillonite (MMT) nanocomposite was prepared by one-pot hydrothermal method. XRD, TEM, Raman, UV–vis, FT-IR, PL and XPS were employed to characterize the nanocomposites. The photocatalytic desulfurization properties of Bi 2 W 1−x Mo x O 6 /MMT nanocomposites were performed by oxidizing dibenzothiophene (DBT) in the model oil under visible light irradiation. Results indicate that the molar fraction of Mo doping has critical impact on the desulfurization rate. Adequate Mo doping may form well-defined “solid solution/co-precipitation” heterostructure of Bi 2 W 1−x Mo x O 6 /Bi 2 MoO 6 , which enhances the visible light absorption efficiency and promotes the separation rate of photogenerated electron-hole pairs, thus leads to the improved photocatalytic desulfurization performance. The desulfurization rate of the model oil can reach 95% when the molar fraction x is 0.7 under visible light irradiation for 3 h. [ABSTRACT FROM AUTHOR]