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Synthesis and Group 4 Complexes of Tris(pyrrolyl-α-methyl)amine.

Authors :
Yanhui Shi
Changsheng Cao
Odom, Aaron L.
Source :
Inorganic Chemistry. 1/12/2004, Vol. 43 Issue 1, p275-281. 7p. 8 Diagrams, 4 Charts.
Publication Year :
2004

Abstract

Studies the synthesis of Tris(pyrrolyl-alpha-methyl)amine and its Group four complexes. Availability of the trianionic ligand tetradentate in a single step by a triple Mannich reaction involving pyrroles, formaldehyde and ammonium chloride; Placement of the ligand on titanium by transmission on Ti(NMe[sub2])[sub4]; Provision of an example of a titanium 2-iminoimidazolidinide.

Details

Language :
English
ISSN :
00201669
Volume :
43
Issue :
1
Database :
Academic Search Index
Journal :
Inorganic Chemistry
Publication Type :
Academic Journal
Accession number :
12212612
Full Text :
https://doi.org/10.1021/ic035049v