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B(C6F5)3-Catalyzed Ring Opening and Isomerization of Unactivated Cyclopropanes.

Authors :
Zhang, Zi ‐ Yu
Liu, Zhi ‐ Yun
Guo, Rui ‐ Ting
Zhao, Yu ‐ Quan
Li, Xiang
Wang, Xiao ‐ Chen
Source :
Angewandte Chemie. 3/27/2017, Vol. 129 Issue 14, p4086-4090. 5p.
Publication Year :
2017

Abstract

Catalytic amounts of B(C6F5)3 promote the ring opening and subsequent isomerization of a series of unactivated cyclopropanes to afford terminal olefins in good yields when a hydrosilane and 2,6-dibromopyridine are employed as additives. [ABSTRACT FROM AUTHOR]

Details

Language :
English
ISSN :
00448249
Volume :
129
Issue :
14
Database :
Academic Search Index
Journal :
Angewandte Chemie
Publication Type :
Academic Journal
Accession number :
121991135
Full Text :
https://doi.org/10.1002/ange.201700864